OCS Ozone Systems — High Capacity

OCS-REFINERY TREAT Phenol & COD Removal System

Remove phenol and high COD load in refinery and petrochemical wastewater with ozone. Designed not to replace biological treatment but to strengthen it.

90%+ COD Removal Capacity Phenol Inhibition Solution Biological Treatment Enhancer High-pH Tolerant Design
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The Problem

Phenol Is Biological Treatment's Biggest Enemy

Refinery wastewater can contain 600–3,000 ppm of phenolic compounds and COD often exceeding 20,000 ppm. Phenol directly suppresses microorganism activity in the biological treatment plant, lowering the efficiency of standard activated-sludge systems.

Microbial Inhibition

Phenol suppresses the activity of microorganisms in biological treatment.

Extremely High COD Load

COD values exceeding 20,000 ppm strain standard treatment capacity.

Aromatic Structure Resistance

Phenol's chemical structure doesn't break down easily with conventional biological processes.

Discharge Limit Risk

Insufficiently treated wastewater risks exceeding tightening discharge standards.

System Concept

Stronger Oxidation, Stronger Biology

OCS-REFINERY TREAT offers a four-stage architecture tailored to refinery scale.

1

Pollutant Profile Analysis

Phenol concentration, COD load, pH and existing biological treatment capacity are assessed.

2

High-Capacity System Design

A kg/hour-scale, high-pH-tolerant ozone system is sized to refinery flow.

3

Ozone + Biological Integration

Ozone is positioned before biological treatment (preventing microbial inhibition) or after (polishing).

4

Catalytic Enhancement (Optional)

For highly resistant loads, catalyst-supported ozonation increases removal efficiency.

Solution Areas

Application Points & Methods

🛢️

Refinery Process Wastewater

Pre-treatment of raw wastewater with high phenol and COD.

  • Protecting biological treatment efficiency by preventing phenol inhibition
  • High-pH-tolerant system design
🧪

Petrochemical Production Wastewater

Aromatic hydrocarbon and refractory organic compound removal.

  • Direct ozone and hydroxyl radical oxidation
  • High effectiveness on refractory compounds
♻️

Ozone-Activated Carbon Polishing

Final treatment stage after biological treatment.

  • Final polishing in multi-stage systems
  • Stronger compliance with discharge limits
🔬

Coking & Special Process Wastewater

Special wastewater with a highly resistant pollutant profile.

  • Catalytic ozonation support
  • Option for combined pre-treatment with coagulation

Technical Data

System Technical Data

Dose Guide
Dose for general COD removal
2–20 g O₃ / m³ wastewater
O₃:COD ratio for refractory organics
0.5–10 g O₃ / g COD
Contact time
5–60 minutes
Proven Performance
COD removal (under optimum conditions)
Up to 90.6%
COD increase with ozone + biological combination
30–50%
Total removal in multi-stage system
Over 94% (COD, BOD₅, ammonia)
System Features
Transfer efficiency (good design)
80–90%
pH tolerance
Design compatible with high pH (including 11)
Catalytic support
Optional (MgO-based, etc.)
Installation & Maintenance
Installation time
Varies by project scale
Service interval
Every 6 months
Warranty
2 years

Why OCS-REFINERY TREAT?

Advantages in Refinery Wastewater

90%+

Proven COD Removal

High effectiveness backed by literature and field data.

Enhancer

Supports Biology, Doesn't Replace It

Protects your existing biological treatment investment and increases its efficiency.

High-pH Compatible

Built for Refinery Conditions

A design suited to the typical high-pH conditions of refinery wastewater.

30-50%

Combination Synergy

The ozone + biological combination markedly increases total removal.

Flexible

Pre- or Post-Treatment

Can be positioned before or after biological treatment.

Engineering

Site-Specific Design

Every project is sized for its phenol and COD profile.

Application Sectors

Which Facilities?

Oil Refineries · Petrochemical Plants · Coking Plants · Chemical Production Facilities

FAQ

Frequently Asked Questions

Does ozone replace my existing biological treatment plant?

No — OCS-REFINERY TREAT is designed to strengthen biological treatment; by breaking down inhibitor compounds like phenol, it lets the biological system run efficiently.

Does performance drop at high pH (e.g. pH 11)?

The system is designed for the typical high-pH conditions of refinery wastewater; performance data shows high removal even under these conditions.

Where should it be applied — before or after biological treatment?

It depends on the pollutant profile. If there's microbial inhibition risk, before; if final polishing is needed, after. The site analysis determines this.

When is catalytic ozonation needed?

For highly resistant loads where standard ozonation falls short, catalyst support can increase removal efficiency.

Can the system be integrated into our existing plant infrastructure?

Yes — it usually integrates into the existing biological treatment line and can be commissioned without major structural change.

Free Feasibility Assessment for Your Facility

Request a free feasibility assessment for your facility. Let's plan the solution that lowers phenol and COD load and strengthens biological treatment.

Request a Free Feasibility Assessment